1. General information
Course:
INORGANIC CHEMISTRY OF SOLID STATE
Code:
57322
Type:
CORE COURSE
ECTS credits:
6
Degree:
398 - UNDERGRADUATE DEGREE PROGRAMME IN CHEMISTRY
Academic year:
2020-21
Center:
1 - FACULTY OF SCIENCE AND CHEMICAL TECHNOLOGY
Group(s):
20
23
Year:
3
Duration:
C2
Main language:
Spanish
Second language:
Use of additional languages:
English Friendly:
Y
Web site:
Bilingual:
N
Lecturer:
RAFAEL FERNANDEZ GALAN
- Group(s):
20
23
Building/Office
Department
Phone number
Email
Office hours
Edificio San Alberto Magno
QUÍMICA INORG., ORG., Y BIOQ.
3494
rafael.fgalan@uclm.es
Lecturer:
FELIX ANGEL JALON SOTES
- Group(s):
20
23
Building/Office
Department
Phone number
Email
Office hours
San Alberto Magno/Planta primera
QUÍMICA INORG., ORG., Y BIOQ.
926052184
felix.jalon@uclm.es
Lecturer:
BLANCA ROSA LOURDES MANZANO MANRIQUE
- Group(s):
20
23
Building/Office
Department
Phone number
Email
Office hours
San Alberto Magno/first floor
QUÍMICA INORG., ORG., Y BIOQ.
926052050
blanca.manzano@uclm.es
Lecturer:
ANA MARIA RODRIGUEZ FERNANDEZ-PACHECO
- Group(s):
20
23
Building/Office
Department
Phone number
Email
Office hours
Politécnico/A23
QUÍMICA INORG., ORG., Y BIOQ.
926051961
anamaria.rfdez@uclm.es
2. Pre-Requisites
Not established
3. Justification in the curriculum, relation to other subjects and to the profession
The subject of Inorganic Chemistry of the Solid State corresponds to the matter of Inorganic Compounds, included in the module of Basic Concepts of Chemistry. It is given in the second semester of the third year of the Bachelor in Chemistry. In this subject, the student is introduced to the basic chemical concepts of the solid state. Along with the acquisition of knowledge in relation with the chemical bonding and the strucutre of solids, it is intended to facilitate the acquisition of knowledge in the main techniques of solid preparation and also in techniques of structural determination, both at a theoretical and at an experimental level (in the practical teaching of the subject). Criteria to deduce some of the solid properties considering the chemical bonding, structure and composition are also given.
4. Degree competences achieved in this course
| Course competences | |
|---|---|
| Code | Description |
| CB02 | Apply their knowledge to their job or vocation in a professional manner and show that they have the competences to construct and justify arguments and solve problems within their subject area. |
| CB04 | Transmit information, ideas, problems and solutions for both specialist and non-specialist audiences. |
| CB05 | Have developed the necessary learning abilities to carry on studying autonomously |
| E03 | Handle chemicals safely and with respect to the environment |
| E06 | Know the structural properties of chemical compounds, including stereochemistry, as well as the main structural research techniques |
| E07 | Relate macroscopic properties with those of atoms, molecules and non-molecular chemical compounds |
| E15 | Know how to handle the standard chemical instrumentation and be able to elaborate and manage standardized procedures of work in the laboratory and chemical industry |
| G01 | Know the principles and theories of Chemistry, as well as the methodologies and applications characteristic of analytical chemistry, physical chemistry, inorganic chemistry and organic chemistry, understanding the physical and mathematical bases that require |
| G02 | Be able to gather and interpret data, information and relevant results, obtain conclusions and issue reasoned reports on scientific, technological or other problems that require the use of chemical tools |
| G03 | Know how to apply the theoretical-practical knowledge acquired in the different professional contexts of Chemistry |
| T05 | Organization and planning capacity |
| T07 | Ability to work as a team and, where appropriate, exercise leadership functions, fostering the entrepreneurial character |
| T10 | Ability to use specific software for chemistry at user level |
| T11 | Ability to obtain bibliographic information, including Internet resources |
5. Objectives or Learning Outcomes
| Course learning outcomes | |
|---|---|
| Description | |
| Apply and interpret some techniques of structural determination or study of properties of molecular and solid inorganic compounds | |
| Apply advanced techniques of preparation of molecular and solid inorganic compounds. | |
| Train the student for autonomous work and learning, as well as for personal initiative | |
| Train the student to search for information, its analysis, interpretation and use for practical purposes. | |
| Know some of the main properties of inorganic solids and relate them to structural aspects | |
| Know the techniques of structural determination for the study of inorganic solids and their surfaces. | |
| Know the most important aspects about the structures of ideal and real inorganic solids. | |
| Know the most important theoretical fundamentals of the chemical bond in inorganic solids | |
| Know the main methods of preparation of inorganic solids | |
| Additional outcomes | |
| Not established. |
6. Units / Contents
-
Unit 1: Introduction to inorganic solids. Solids stability. Solids preparation methods: solid state reactions, crystallization of melts, glasses and gels, vapor phase transport, modification of structures by ion exchange and interstitial reactions, hydrothermal and high pressure methods, electrochemical reduction methods. Methods of preparing thin sheets.
-
Unit 2: Crystal structures. Compact packing. Hole occupation and structural types. Internal coordinates of the unit cell. Condensed polyhedra. Miller indices.
-
Unit 3: Solids structural determination techniques. Thermal methods. X-ray diffraction. Electron microscopy.
-
Unit 4: The chemical bond in solids I. Ionic model. Ratio of radii and limitations. Partially covalent bonds. Mooser-Pearson graphs.
-
Unit 5: The chemical bond in solids II. Band theory. Bloch functions. Brillouin zones. Bands structure for conductors, insulators and semiconductors. Effect of temperature on electrical conduction.
-
Unit 6: Crystal defects. Point, line (dislocations), two-dimensional defects, grain defects. Not stoichiometry. Solid solutions: substitutional, interstitial and complex.
-
Unit 7: LABORATORY WORK. Preparation of a silicone. Preparation of coloured glasses. Preparation of a type A zeolite. Preparation of magnetite and zinc ferrite.
7. Activities, Units/Modules and Methodology
| Training Activity | Methodology | Related Competences (only degrees before RD 822/2021) | ECTS | Hours | As | Com | Description | |
| Class Attendance (theory) [ON-SITE] | Lectures | E06 E07 G01 G03 | 1.16 | 29 | N | N | ||
| Class Attendance (practical) [ON-SITE] | Practical or hands-on activities | E03 E15 G03 T05 | 0.8 | 20 | Y | Y | ||
| Problem solving and/or case studies [ON-SITE] | Guided or supervised work | G02 G03 T10 T11 | 0.24 | 6 | Y | N | ||
| In-class Debates and forums [ON-SITE] | Group tutoring sessions | E06 E07 G01 G02 G03 | 0.08 | 2 | N | N | ||
| Writing of reports or projects [OFF-SITE] | Self-study | G03 T05 T07 T10 T11 | 2.48 | 62 | Y | Y | ||
| Study and Exam Preparation [OFF-SITE] | Self-study | E06 E07 E15 G01 G02 G03 | 1.12 | 28 | N | N | ||
| Final test [ON-SITE] | Self-study | E06 E07 E15 G01 G02 G03 | 0.08 | 2 | Y | Y | ||
| Progress test [ON-SITE] | Self-study | E06 E07 E15 G01 G02 G03 | 0.04 | 1 | Y | N | ||
| Total: | 6 | 150 | ||||||
| Total credits of in-class work: 2.4 | Total class time hours: 60 | |||||||
| Total credits of out of class work: 3.6 | Total hours of out of class work: 90 | |||||||
As: Assessable training activity Com: Training activity of compulsory overcoming (It will be essential to overcome both continuous and non-continuous assessment).
8. Evaluation criteria and Grading System
| Evaluation System | Continuous assessment | Non-continuous evaluation * | Description |
| Progress Tests | 35.00% | 0.00% | If in these tests a grade greater than or equal to 5 (out of 10) is reached, it will not be necessary to carry out this part in the final test. |
| Laboratory sessions | 20.00% | 20.00% | Experimental work in the laboratory will be evaluated: attitude, scripts, skill and a practical exam after the face-to-face sessions. A grade of 5 must be reached to pass the course. |
| Assessment of problem solving and/or case studies | 10.00% | 0.00% | It will be evaluated (1) In the selection of materials for the preparation of a written seminar: originality and adaptation to the topic, leadership capacity, ability to work in groups, adaptation of the seminar to the time of exposition. (2)) In the elaboration of a written work in which the answers to the proposed seminar are included: adequate answer to the questions of the seminar, editorial adequacy that makes this work understandable for the study of the seminar, leadership capacity, ability to team work. (3) In the class presentation of the seminar: adaptation of the computer media, clarity of the presentation, interaction with the audience, making the seminar participatory. |
| Final test | 35.00% | 80.00% | There will be a written exam of the second half of the subject. Students who have not passed the progress test must attend a written exam of the entire course. For these students the assessment of the final test will be 70%. It is necessary to achieve a grade of 5 in each of the two halves of the subject to pass the subject and to average with the rest of the activities. |
| Total: | 100.00% | 100.00% |
According to art. 4 of the UCLM Student Evaluation Regulations, it must be provided to students who cannot regularly attend face-to-face training activities the passing of the subject, having the right (art. 12.2) to be globally graded, in 2 annual calls per subject , an ordinary and an extraordinary one (evaluating 100% of the competences).
Evaluation criteria for the final exam:
-
Continuous assessment:See previous table
-
Non-continuous evaluation:The student must carry out the practical laboratory activities in person. Their performance in the laboratory will be evaluated, as well as a written practical exam. The student must pass this part of the course, which is 20% of the grade. The exam corresponding to the theoretical part represents 80% of the final grade.
Specifications for the resit/retake exam:
In this call, the grade acquired in those tests that have passed 5 (out of 10) during the same academic year will be kept. The qualification of the practical sessions will be kept for the time indicated by the regulations if they have been passed (minimum 5)
Specifications for the second resit / retake exam:
Evaluation criteria not defined
9. Assignments, course calendar and important dates
| Not related to the syllabus/contents | |
|---|---|
| Hours | hours |
| Unit 1 (de 7): Introduction to inorganic solids. Solids stability. Solids preparation methods: solid state reactions, crystallization of melts, glasses and gels, vapor phase transport, modification of structures by ion exchange and interstitial reactions, hydrothermal and high pressure methods, electrochemical reduction methods. Methods of preparing thin sheets. | |
|---|---|
| Activities | Hours |
| Class Attendance (theory) [PRESENCIAL][Lectures] | 5 |
| Problem solving and/or case studies [PRESENCIAL][Guided or supervised work] | 1 |
| In-class Debates and forums [PRESENCIAL][Group tutoring sessions] | .3 |
| Writing of reports or projects [AUTÓNOMA][Self-study] | 8.5 |
| Study and Exam Preparation [AUTÓNOMA][Self-study] | 4.5 |
| Final test [PRESENCIAL][Self-study] | .3 |
| Progress test [PRESENCIAL][Self-study] | .14 |
| Unit 2 (de 7): Crystal structures. Compact packing. Hole occupation and structural types. Internal coordinates of the unit cell. Condensed polyhedra. Miller indices. | |
|---|---|
| Activities | Hours |
| Class Attendance (theory) [PRESENCIAL][Lectures] | 5 |
| Problem solving and/or case studies [PRESENCIAL][Guided or supervised work] | 1 |
| In-class Debates and forums [PRESENCIAL][Group tutoring sessions] | .3 |
| Writing of reports or projects [AUTÓNOMA][Self-study] | 8.5 |
| Study and Exam Preparation [AUTÓNOMA][Self-study] | 4.1 |
| Final test [PRESENCIAL][Self-study] | .3 |
| Progress test [PRESENCIAL][Self-study] | .16 |
| Unit 3 (de 7): Solids structural determination techniques. Thermal methods. X-ray diffraction. Electron microscopy. | |
|---|---|
| Activities | Hours |
| Class Attendance (theory) [PRESENCIAL][Lectures] | 7 |
| Problem solving and/or case studies [PRESENCIAL][Guided or supervised work] | 1 |
| In-class Debates and forums [PRESENCIAL][Group tutoring sessions] | .3 |
| Writing of reports or projects [AUTÓNOMA][Self-study] | 9.5 |
| Study and Exam Preparation [AUTÓNOMA][Self-study] | 4.1 |
| Final test [PRESENCIAL][Self-study] | .3 |
| Progress test [PRESENCIAL][Self-study] | .16 |
| Unit 4 (de 7): The chemical bond in solids I. Ionic model. Ratio of radii and limitations. Partially covalent bonds. Mooser-Pearson graphs. | |
|---|---|
| Activities | Hours |
| Class Attendance (theory) [PRESENCIAL][Lectures] | 4 |
| Problem solving and/or case studies [PRESENCIAL][Guided or supervised work] | 1 |
| In-class Debates and forums [PRESENCIAL][Group tutoring sessions] | .3 |
| Writing of reports or projects [AUTÓNOMA][Self-study] | 8.5 |
| Study and Exam Preparation [AUTÓNOMA][Self-study] | 4.1 |
| Final test [PRESENCIAL][Self-study] | .3 |
| Progress test [PRESENCIAL][Self-study] | .16 |
| Unit 5 (de 7): The chemical bond in solids II. Band theory. Bloch functions. Brillouin zones. Bands structure for conductors, insulators and semiconductors. Effect of temperature on electrical conduction. | |
|---|---|
| Activities | Hours |
| Class Attendance (theory) [PRESENCIAL][Lectures] | 3 |
| Problem solving and/or case studies [PRESENCIAL][Guided or supervised work] | 1 |
| In-class Debates and forums [PRESENCIAL][Group tutoring sessions] | .3 |
| Writing of reports or projects [AUTÓNOMA][Self-study] | 8.5 |
| Study and Exam Preparation [AUTÓNOMA][Self-study] | 4.1 |
| Final test [PRESENCIAL][Self-study] | .3 |
| Progress test [PRESENCIAL][Self-study] | .16 |
| Unit 6 (de 7): Crystal defects. Point, line (dislocations), two-dimensional defects, grain defects. Not stoichiometry. Solid solutions: substitutional, interstitial and complex. | |
|---|---|
| Activities | Hours |
| Class Attendance (theory) [PRESENCIAL][Lectures] | 5 |
| Problem solving and/or case studies [PRESENCIAL][Guided or supervised work] | 1 |
| In-class Debates and forums [PRESENCIAL][Group tutoring sessions] | .3 |
| Writing of reports or projects [AUTÓNOMA][Self-study] | 8.5 |
| Study and Exam Preparation [AUTÓNOMA][Self-study] | 4.1 |
| Final test [PRESENCIAL][Self-study] | .3 |
| Progress test [PRESENCIAL][Self-study] | .16 |
| Unit 7 (de 7): LABORATORY WORK. Preparation of a silicone. Preparation of coloured glasses. Preparation of a type A zeolite. Preparation of magnetite and zinc ferrite. | |
|---|---|
| Activities | Hours |
| Class Attendance (practical) [PRESENCIAL][Practical or hands-on activities] | 20 |
| In-class Debates and forums [PRESENCIAL][Group tutoring sessions] | .2 |
| Writing of reports or projects [AUTÓNOMA][Self-study] | 10 |
| Study and Exam Preparation [AUTÓNOMA][Self-study] | 3 |
| Final test [PRESENCIAL][Self-study] | .2 |
| Progress test [PRESENCIAL][Self-study] | .06 |
| Global activity | |
|---|---|
| Activities | hours |
10. Bibliography and Sources
| Author(s) | Title | Book/Journal | Citv | Publishing house | ISBN | Year | Description | Link | Catálogo biblioteca |
|---|---|---|---|---|---|---|---|---|---|
| A. K.Cheetham and Peter Day | Solid State Chemistry: techniques | Libro | Oxford | Oxfor Science publications | 0-19-855286-6 | 2001 | libro de consulta específico | http://biblioteca.uclm.es | |
| A. K.Cheetham and Peter Day | Solid State Chemistry | Libro | Oxford | Clarendon Press | 0-19-855166-5 | 2001 | Libro de consulta específico | http://biblioteca.uclm.es | |
| Cotton, Frank Albert | Química Inorgánica Avanzada | Libro | Mexico | Limusa, cop. | 968-18-1795-8 | 1995 | Libro de consulta específico | http://biblioteca.uclm.es | |
| DUFFY, J. A. | Bonding, energy levels and bands in inorganic solids | Libro | Essex | Longman Scientific & Technical | 0-582-03495-7 | 1990 | Libro de consulta específico | http://biblioteca.uclm.es | |
| Dwight, Kirby | Solid State Chemistry : synthesis, structure, and properties of selected oxides and sulfides | Libro | New York | Chapman & Hall | 0-412-03611-5 | 1993 | Libro de consulta general | ||
| Greenwood, N. N. | Chemistry of the elements | Libro | Amsterdam | Butterworth-Heinemann | 978-0-7506-3365-9 | 2008 | Libro de consulta general | http://biblioteca.uclm.es | |
| Müller, Ulrich | Inorganic Structural Chemistry | Libro | New York | John Wiley & Sons | 0-471-93717-7 | 1992 | Libro de consulta específico | http://biblioteca.uclm.es | |
| Rankin, David W. H. | Structural Methods in Inorganic Chemistry | Libro | Oxford | Blackwell Scientific | 0-632-02963-3 | 1994 | Libro de consulta específico | http://biblioteca.uclm.es | |
| Rao, C.N.R. | New directions in solid state chemistry | Libro | Cambridge | Cambridge University Press | 0-521-49907-0 | 2004 | Libro de consulta general | http://biblioteca.uclm.es | |
| Smart, Lesley | Solid State Chemistry | Libro | New York | Taylor & Francis | 0-7487-7516-1 | 2005 | libro de consulta importante | http://biblioteca.uclm.es | |
| Smith, William F | Fundamentos de la ciencia e ingeniería de materiales | Libro | Maqdrid | McGraw-Hill Interamerican | 978-607-15-1152-2 | 2010 | Libro de consulta importante | hhttp://biblioteca.uclm.es/ | |
| Wells, A. F | Quimica Inorganica Estructural | Libro | Barcelona | Reverté | 84-291-7524-5 | 1978 | Libro de consulta general | http://biblioteca.uclm.es | |
| West , A. R. | Basic Solid State Chemistry | Libro | New York | John Wiley and Sons | 0-471-98755-7 | 1999 | Libro de consulta importante | http://biblioteca.uclm.es/ | |
| West, A. R. | Solid State Chemistry | Libro | New York | John Wiley and Sons | 0-471-90874-6 | Libro de consulta importante | http://biblioteca.uclm.es |