1. General information
Course:
ADVANCED TECHNIQUES OF STRUCTURAL DETERMINATION
Code:
310590
Type:
ELECTIVE
ECTS credits:
6
Degree:
2326 - MASTER DEGREE PROGRAMME IN CHEMICAL RESEARCH
Academic year:
2019-20
Center:
1 - FACULTY OF SCIENCE AND CHEMICAL TECHNOLOGY
Group(s):
20
Year:
1
Duration:
C2
Main language:
Spanish
Second language:
English
Use of additional languages:
English Friendly:
Y
Web site:
Bilingual:
N
Lecturer:
ANTONIO DE LA HOZ AYUSO
- Group(s):
20
Building/Office
Department
Phone number
Email
Office hours
San Alberto Magno
QUÍMICA INORG., ORG., Y BIOQ.
926295411
antonio.hoz@uclm.es
Lunes,Martes y Jueves 10 a 12 h
Lecturer:
BLANCA ROSA LOURDES MANZANO MANRIQUE
- Group(s):
20
Building/Office
Department
Phone number
Email
Office hours
San Alberto Magno/first floor
QUÍMICA INORG., ORG., Y BIOQ.
926052050
blanca.manzano@uclm.es
Monday,wednesday 16.30 to 18.30 h
tuesday and thurday
19:00-20:00
Lecturer:
ANA MARIA RODRIGUEZ FERNANDEZ-PACHECO
- Group(s):
20
Building/Office
Department
Phone number
Email
Office hours
Politécnico/A23
QUÍMICA INORG., ORG., Y BIOQ.
926051961
anamaria.rfdez@uclm.es
Se anunciará a través del Moodle a principio de curso
2. Pre-Requisites
Not established
3. Justification in the curriculum, relation to other subjects and to the profession
Not established
4. Degree competences achieved in this course
| Course competences | |
|---|---|
| Code | Description |
| E05 | Knowing the usefulness of separation techniques, analysis and structural determination, their joint application in the resolution of research problems, as well as possessing skills in the use of such techniques. |
| E06 | Knowing the main concepts and applications of coordination and organometallic chemistry. |
| E07 | Knowing the principles of sustainable chemistry and safety standards for handling known chemicals |
| E08 | Knowing the kinetics of chemical processes, including catalysis, reaction mechanisms and the methods and techniques used to determine them. |
| E10 | Being able to address synthesis problems, including planning and development of preparation of compounds with new properties, methods of control of selectivity, especially the stereoselective methods. |
| G01 | Knowing the precision of the experimental data and its use for the planning of experimental research work. |
| T02 | Ability to work in a team and to exercise leadership functions, fostering the entrepreneurial character |
| T04 | Ability to use specific software for research in chemistry. |
| T05 | Ability to obtain bibliographic information at the research level, including Internet resources (databases, specialized scientific bibliography, social networks, etc ...), as well as carry out a selection and classification of it. |
| T06 | Being able to develop professionally through continuous training. |
5. Objectives or Learning Outcomes
| Course learning outcomes | |
|---|---|
| Description | |
| Knowing the effect of radio frequency pulses in NMR. | |
| Knowing the phenomenon of X-ray diffraction applied to the determination of structures from monocrystals. | |
| Knowing the foundation and the information they provide different techniques, both electron microscopy and spectroscopic characterization of surfaces and coordination compounds. | |
| Knowing the main methods of transfer sensitivity. | |
| Knowing the most advanced techniques of NMR resonance solid, gradients, reverse resonance image, diffusion. | |
| Manage software for processing and simulation of NMR. | |
| Knowing how to handle crystallographic data bases and data processing programs structures determined by X-ray diffraction. | |
| Knowing how to use the appropriate techniques and obtain information for the characterization of catalysts and precatalysts. | |
| Being able to analyze the information provided by a particular technique in order to deduce the structure of the derivative under study and know how to select and apply the technique most suitable for each type of structural analysis characterization. | |
| Knowing the origin of the information transmitted in mono and two-dimensional techniques. | |
| Knowing the major applications monkey sequences and two dimensional pulses. | |
| Additional outcomes | |
| Not established. |
6. Units / Contents
-
Unit 1:
-
Unit 2:
-
Unit 3:
-
Unit 4:
-
Unit 5:
-
Unit 6:
-
Unit 7:
-
Unit 8:
-
Unit 9:
-
Unit 10:
-
Unit 11:
7. Activities, Units/Modules and Methodology
| Training Activity | Methodology | Related Competences (only degrees before RD 822/2021) | ECTS | Hours | As | Com | R | Description * |
| Class Attendance (theory) [ON-SITE] | Lectures | E05 E06 E08 E10 G01 T06 | 0.92 | 23 | Y | Y | Y | |
| Workshops or seminars [ON-SITE] | Guided or supervised work | E05 E06 E08 E10 G01 T02 T05 T06 | 0.64 | 16 | Y | Y | Y | |
| Group tutoring sessions [ON-SITE] | Group tutoring sessions | E05 E08 E10 G01 T06 | 0.16 | 4 | Y | N | Y | |
| Writing of reports or projects [OFF-SITE] | Self-study | E05 E08 E10 G01 T02 T05 T06 | 3.8 | 95 | Y | N | Y | |
| Study and Exam Preparation [OFF-SITE] | Self-study | E05 E08 E10 G01 T05 T06 | 0.4 | 10 | Y | N | Y | |
| Progress test [ON-SITE] | Assessment tests | E05 E08 E10 G01 T05 T06 | 0.08 | 2 | Y | N | Y | |
| Total: | 6 | 150 | ||||||
| Total credits of in-class work: 1.8 | Total class time hours: 45 | |||||||
| Total credits of out of class work: 4.2 | Total hours of out of class work: 105 | |||||||
As: Assessable training activity Com: Training activity of compulsory overcoming R: Rescheduling training activity
8. Evaluation criteria and Grading System
| Grading System | |||
| Evaluation System | Face-to-Face | Self-Study Student | Description |
| Assessment of active participation | 10.00% | 0.00% | |
| Assessment of problem solving and/or case studies | 30.00% | 20.00% | |
| Theoretical papers assessment | 25.00% | 20.00% | |
| Oral presentations assessment | 20.00% | 10.00% | |
| Final test | 15.00% | 50.00% | |
| Total: | 100.00% | 100.00% | |
Evaluation criteria for the final exam:
Evaluation criteria not defined
Specifications for the resit/retake exam:
Evaluation criteria not defined
Specifications for the second resit / retake exam:
Evaluation criteria not defined
9. Assignments, course calendar and important dates
| Not related to the syllabus/contents | |
|---|---|
| Hours | hours |
| Unit 1 (de 11): | |
|---|---|
| Activities | Hours |
| Class Attendance (theory) [PRESENCIAL][Lectures] | 2 |
| Writing of reports or projects [AUTÓNOMA][Self-study] | 3.1 |
| Study and Exam Preparation [AUTÓNOMA][Self-study] | .46 |
| Unit 2 (de 11): | |
|---|---|
| Activities | Hours |
| Class Attendance (theory) [PRESENCIAL][Lectures] | 4 |
| Writing of reports or projects [AUTÓNOMA][Self-study] | 6.2 |
| Study and Exam Preparation [AUTÓNOMA][Self-study] | .92 |
| Unit 3 (de 11): | |
|---|---|
| Activities | Hours |
| Class Attendance (theory) [PRESENCIAL][Lectures] | 5 |
| Writing of reports or projects [AUTÓNOMA][Self-study] | 7.75 |
| Study and Exam Preparation [AUTÓNOMA][Self-study] | 1.15 |
| Unit 4 (de 11): | |
|---|---|
| Activities | Hours |
| Class Attendance (theory) [PRESENCIAL][Lectures] | 1 |
| Writing of reports or projects [AUTÓNOMA][Self-study] | 1.55 |
| Study and Exam Preparation [AUTÓNOMA][Self-study] | .23 |
| Unit 5 (de 11): | |
|---|---|
| Activities | Hours |
| Class Attendance (theory) [PRESENCIAL][Lectures] | 3 |
| Group tutoring sessions [PRESENCIAL][Group tutoring sessions] | 1 |
| Writing of reports or projects [AUTÓNOMA][Self-study] | 4.65 |
| Study and Exam Preparation [AUTÓNOMA][Self-study] | .69 |
| Unit 6 (de 11): | |
|---|---|
| Activities | Hours |
| Workshops or seminars [PRESENCIAL][Guided or supervised work] | 12 |
| Group tutoring sessions [PRESENCIAL][Group tutoring sessions] | 1 |
| Writing of reports or projects [AUTÓNOMA][Self-study] | 18.6 |
| Study and Exam Preparation [AUTÓNOMA][Self-study] | 2.76 |
| Progress test [PRESENCIAL][Assessment tests] | 3 |
| Unit 7 (de 11): | |
|---|---|
| Activities | Hours |
| Class Attendance (theory) [PRESENCIAL][Lectures] | 2 |
| Workshops or seminars [PRESENCIAL][Guided or supervised work] | 2 |
| Writing of reports or projects [AUTÓNOMA][Self-study] | 6.2 |
| Study and Exam Preparation [AUTÓNOMA][Self-study] | .92 |
| Unit 8 (de 11): | |
|---|---|
| Activities | Hours |
| Class Attendance (theory) [PRESENCIAL][Lectures] | 3 |
| Workshops or seminars [PRESENCIAL][Guided or supervised work] | 4 |
| Group tutoring sessions [PRESENCIAL][Group tutoring sessions] | 1 |
| Writing of reports or projects [AUTÓNOMA][Self-study] | 9.3 |
| Study and Exam Preparation [AUTÓNOMA][Self-study] | 1.38 |
| Unit 9 (de 11): | |
|---|---|
| Activities | Hours |
| Class Attendance (theory) [PRESENCIAL][Lectures] | 2 |
| Workshops or seminars [PRESENCIAL][Guided or supervised work] | 2 |
| Group tutoring sessions [PRESENCIAL][Group tutoring sessions] | 1 |
| Writing of reports or projects [AUTÓNOMA][Self-study] | 7.75 |
| Study and Exam Preparation [AUTÓNOMA][Self-study] | 1.15 |
| Unit 10 (de 11): | |
|---|---|
| Activities | Hours |
| Class Attendance (theory) [PRESENCIAL][Lectures] | 2 |
| Workshops or seminars [PRESENCIAL][Guided or supervised work] | 2 |
| Writing of reports or projects [AUTÓNOMA][Self-study] | 6.2 |
| Study and Exam Preparation [AUTÓNOMA][Self-study] | .92 |
| Unit 11 (de 11): | |
|---|---|
| Activities | Hours |
| Class Attendance (theory) [PRESENCIAL][Lectures] | 1 |
| Workshops or seminars [PRESENCIAL][Guided or supervised work] | 3 |
| Group tutoring sessions [PRESENCIAL][Group tutoring sessions] | 1 |
| Writing of reports or projects [AUTÓNOMA][Self-study] | 6.2 |
| Study and Exam Preparation [AUTÓNOMA][Self-study] | .92 |
| Progress test [PRESENCIAL][Assessment tests] | 3 |
| Global activity | |
|---|---|
| Activities | hours |
10. Bibliography and Sources
| Author(s) | Title | Book/Journal | Citv | Publishing house | ISBN | Year | Description | Link | Catálogo biblioteca |
|---|---|---|---|---|---|---|---|---|---|
| A. K. Cheetham, P. Day | Solid State Chemistry | Oxford University Press | 5 | 1991 | |||||
| A. R. West | Basic Solid State Chemistry | WILEY | 0-471-91798-2 | 1984 |
|
||||
| F. A. Cotton | La teoría de grupos aplicada a la química | Mexico | Limusa | 968-18-1047-3 |
|
||||
| H. Friebolin | Basic One- and Two Dimensional NMR Spectroscopy | WILEY | 978-3-527-32782-9 | 2016 | https://www.wiley.com/en-us/Basic+One+and+Two+Dimensional+NMR+Spectroscopy%2C+5th%2C+Completely+Revised+and+Updated+Edition-p-9783527327829 | ||||
| H. Günther | NMR Spectroscopy | WILEY | 978-3-527-33004-1 | 2013 | https://www.wiley.com/en-us/NMR+Spectroscopy%3A+Basic+Principles%2C+Concepts+and+Applications+in+Chemistry%2C+3rd+Edition-p-9783527330003 | ||||
| J. C. Vickerman, I. S. Gimore, Eds. | Surface Analysis. The Principal Techniques | Chichester | Wiley | 9780470017630 | 2009 | ||||
| J. M. Albella, A. M. Cintas, T. Miranda, J. M. Serratosa | Introducción a la Ciencia de materiales. Técnicas de preparación y caracterización | CSIC | 84-00-07343-6 | 1993 | |||||
| J. M. Thomas, W. J. Thomas | Principles and Practice of Heterogeneous Catalysis | VCH | 3-527-29239-X | 1997 |
|
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| Jenny P. Glusker; Mitchell Lewis and Miriam Rossi | Crystal Structure Analysis for Chemists and Biologists | VCH | 0-89573-273-4 | 1994 |
|
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| M. Martínez-Ripoll, F. Hernández-Cano | Cristalografía | 2016 | http://www.xtal.iqfr.csic.es/Cristalografia/index.html | ||||||
| R. Freeman | Magnetic Resonance in Chemistry and Medicine | Oxford University Press | 0-19-926225-X | 2005 | https://global.oup.com/academic/product/magnetic-resonance-in-chemistry-and-medicine-9780199262250?cc=es&lang=en& | ||||
| S. Berger, S. Braun | 200 and More NMR Experiments: A Practical Course | VCH | 978-3-527-31067-8 | 2004 | https://www.wiley.com/en-us/200+and+More+NMR+Experiments%3A+A+Practical+Course-p-9783527310678 |